Tool-wear effects of anionic components of urea-formaldehyde resins used as particleboard binders

Tool-wear effects of chloride, sulfate, and a few other components of catalysts normally added to particleboard (PB) binder urea-formaldehyde (UP) resins were evaluated by bonding PBs and testing them with a tungsten carbide (C2) knife. At the normal 0.4 and 0.8 percent addition levels, ammonium chloride showed the highest tool-wear effect and ammonium sulfate the lowest. Both sodium chloride and sodium sulfate showed mild tool-wear effects at the 2.0 percent level, but showed high tool-wear effects at the 5.0 percent level, with the former having a greater effect than the latter. Sodium salts of oxalic and nitric acid in UF resins and sodium hydroxide in phenol-formaldehyde (PF) resin also showed increased tool-wear effects. Both the acidity and basicity of catalyst additives and the active involvement of certain additive elements it corrosion/oxidation wearing processes of tool metals appear to cause the excess tool-wear effects observed.

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